Kristian Birk Buhl, Asger Holm Agergaard, Mie Lillethorup, Jakob Pagh Nikolajsen, Steen Uttrup Pedersen, Kim Daasbjerg https://doi.org/10.3390/polym12071475 Creating strong joints between dissimilar materials for high-performance hybrid products places high demands on modern adhesives. Traditionally, adhesion relies on the compatibility between surfaces, often requiring the use of primers and thick bonding layers to achieve stable joints.…
Kristian B Buhl, Asger H Agergaard, Rasmus K Møller, Mikkel Kongsfelt, Simon Heide-Jørgensen, Michal K Budzik, Mogens Hinge, Steen U Pedersen, Kim Daasbjerg https://doi.org/10.1021/acsapm.0c00306 Creating interchain cross-links can improve the stability and robustness of polymer brushes. Unfortunately, the synthetic strategies required for this are often tedious and time-consuming, making their scale-up difficult, if not impossible.…
Paolo Lamagni, Matteo Miola, Jacopo Catalano, Mathias S Hvid, Mohammad Aref H Mamakhel, Mogens Christensen, Monica R Madsen, Henrik S Jeppesen, Xin‐Ming Hu, Kim Daasbjerg, Troels Skrydstrup, Nina Lock https://doi.org/10.1002/adfm.201910408 Recently, a large number of nanostructured metal‐containing materials have been developed for the electrochemical CO2 reduction reaction (eCO2RR). However, it remains a challenge to achieve high…
Monica R Madsen, Joakim B Jakobsen, Magnus H Rønne, Hongqing Liang, Hans Christian D Hammershøj, Peter Nørby, Steen U Pedersen, Troels Skrydstrup, Kim Daasbjerg https://doi.org/10.1021/acs.organomet.9b00815 Carbon dioxide utilization through electrocatalysis is a promising pathway toward a more sustainable future. In this work the electrocatalytic reduction of carbon dioxide by ReI and RuIIbipyridine complexes bearing pendant amines…
Amir Reza Abbasi, Mohammadreza Yousefshahi, Kim Daasbjerg https://doi.org/10.1007/s10904-020-01452-6 Herein, we introduce a simple set of experiments to construct non-enzymatic glucose sensors. The modification procedure was initiated by electrodeposition of nickel-coordination polymers (denoted henceforth as Ni-CPs) at the surface of glassy carbon (GC) electrode decorated with carbonnanotubes (CNTs). The electrochemical sensing of glucose occurred through the…
K Domino, MB Johansen, K Daasbjerg, T Skrydstrup https://doi.org/10.1021/acs.organomet.9b00849 We have performed a series of stoichiometric studies in order to identify viable steps for a hypothetical catalytic cycle for the palladium-mediated carbonylative coupling of an aryl bromide with TMSCF3. Our work revealed that benzoyl Pd(II) complexes bearing Xantphos or tBu3P as the phosphine ligands, which are…
Magnus H Rønne, Dasol Cho, Monica R Madsen, Joakim B Jakobsen, Seunghwan Eom, Émile Escoudé, Hans Christian D Hammershøj, Dennis U Nielsen, Steen U Pedersen, Mu-Hyun Baik, Troels Skrydstrup, Kim Daasbjerg https://doi.org/10.1021/jacs.9b11806 Electrocatalysis is a promising tool for utilizing carbon dioxide as a feedstock in the chemical industry. However, controlling the selectivity for different CO2 reduction…
Xiaoyu Chen, Xin-Ming Hu, Kim Daasbjerg, Mårten SG Ahlquist https://doi.org/10.1021/acs.organomet.9b00726 Adhering a cobalt porphyrin (Co(TPP)) catalyst on a carbon nanotube (CNT) supporting material greatly enhances its reactivity and enables catalysis in water, which is otherwise impossible. However, the effect of solvent as well as supporting materials on catalysis is still elusive. On the basis of…
Asger Holm Agergaard, Steen Uttrup Pedersen, Henrik Birkedal, Kim Daasbjerg 10.1039/d0py00916d Catecholato-metal complexes are widely used in functional materials such as hydrogels, where the dynamic nature of the coordination bonds between catechol and metal ions contributes to self-healing and stimuli-responsive properties. Herein, we translate the pH-controlled speciation of such complexes known from bulk to a…
Andreas Sommerfeldt, Kim Daasbjerg, Steen Uttrup Pedersen, Sunirmal Pal https://doi.org/10.1021/acs.macromol.0c00861 Self-immolative polymers (SIPs) are promising members of the emerging class of recyclable polymers with the ability to end-to-end depolymerize to their monomers. Unfortunately, SIPs are often synthesized by cumbersome procedures at low temperatures in protected atmosphere. In this study, a SIP with a novel poly(disulfide)…